Chloride stress corrosion cracking ssina specialty steel. Stainless steels are more resistant to general corrosion compared with carbon steel. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. This mode of attack is termed stress corrosion cracking scc.
Stress corrosion of type 304 stainless steel in chloride. Lean duple stainless steel product description ak steel nitronic 19d stainless steel is a lean duplex stainless steel with a mixed ferrite and austenite structure. Mar 11, 2020 this research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. Corrosive conditions for stainless steel can be the chloride depositions from a marine atmosphere on the steel surface in a humid atmosphere these, conditions may alter the choice of steel grade to a more corrosion resistant alloy. The elbow was welded with two straight pipes at two ends. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Pitting corrosion crevice corrosion stress corrosion cracking pitting corrosion tends to be associated with free surfaces of stainless steel. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Although no stainless steel grade is totally immune.
The effects of dissolved oxygen content in the water, heat treatment, especially slight sensitization, and most importantly chloride ion concentration on the susceptibility of type 304 stainless steel to stress corrosion cracking scc were investigated. There are three main types of localised corrosion mechanisms that can affect stainless steels. Stress corrosion cracking scc is a common issue with many specialty alloys. Influence of high temperature on corrosion behavior of 304. This together with slightly higher stacking fault energy schramm and reed 1975 are the main reasons for better resistance of type 316316l stainless steel than type 304 304l to stress corrosion cracking in sodium chloride solutions. Chloride stress corrosion cracking in austenitic stainless steel.
The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. F kjkg it has superior chloride stress corrosion cracking resistance to types 304 and 316. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking of an austenitic stainless steel in. Chloride stress corrosion cracking and 316 stainless steel. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Stress corrosion cracking facts and how to reduce the risk. What is the maximum chloride in ppm that can be allowed in. Austenitic type 304 uns s30400 stainless steel is susceptible to stress corrosion cracking scc in acidic chloride cl.
Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Constant extension rate experiments have been performed on type 304 stainless steel round tensiontest specimens in 35 percent magnesium chloride at 120c as a function of electrode potential and extension rate. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Chloride induced stress corrosion cracking of type 304. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Corrosion of stainless steels in supply drinking and waste. Stress corrosion cracking of type 304 austenitic stainless. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f.
Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The failure of a bellow expansion joint of 304 stainless steel has been analysed. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing conditions in the water. This alloy provides high yield strength, good drawing and welding characteristics, excellent chloride stress corrosion cracking resistance, and high cyclic oxidation resistance. Cracks were located mainly at positions close to the weld joint and the arc where very strong tensile residual stress existed. Chloride ions promoted scc of both annealed and sensitized type 304 stainless steel in high temperature water containing high dissolved oxygen at 286 c. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. On the stress corrosion cracking and hydrogen embrittlement. The objective of this work is to evaluate if atmospheric stress corrosion cracking can develop in stainless steel cask. Stress corrosion cracking susceptibility of 304l substrate and. Because many of the dry storage containers are made of austenitic stainless steels, a potential concern is the susceptibility of the canisters to undergo chloride induced stress corrosion cracking. There is a synergistic relationship between dissolved oxygen and the chloride level.
With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Type 304 stainless steel an overview sciencedirect topics. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Jun 10, 2016 310s is an austenitic stainless steel for high temperature applications, having strong resistance of oxidation, hydrogen embrittlement and corrosion. A strain rate of 5 x 10sup 4 minutesup 1 was employed. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Pdf failure of 304 stainless bellows expansion joint. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. Stress corrosion cracking of austenitic type 304 stainless. Stress corrosion cracking of aisi 304 and aisi 316.
Type 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. Corrosion of unprotected carbon steel occurs even inside reinforced. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. The combination of tensile stress and a specific corrosive environment can crack stainless steels.
Methods of minimizing chloride stress corrosion cracking. Austenitic steels of type astm 304 and 316 austenitic steels have limited. The type of corrosion is most commonly local in the presence of chlorides, i. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. Stress corrosion cracking scc caused by wet hydrogen sulfide was responsible for the failure. Stress corrosion cracking scc is the main corrosion failure mode for 310s stainless steel. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Effects of temperature and pressure on stress corrosion. Duplex grades are usually divided into three subgroups based on their corrosion resistance. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Chloride induced stress corrosion cracking of type 304 and. The stress corrossion behavior of aisi type 304 stainless steel was investigated as a function of the environmental variables, temperature, ph, cation species, and chloride concentration in concentrated solutions of mgcl 2, cacl 2 and licl the time to failure at a constant stress, chloride ion concentration, and temperature increased in the order mgcl 2, cacl 2, licl.
There is an additional risk of stress corrosion cracking scc at higher temperatures. Deterioration by clscc can lead to failures that have the potential to release. When potentiostatic measurement was applied, an extension rate of 4. The standard 304 304l and 316316l grades are most susceptible. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Effect of halogens and inhibitors on the external stress.
Specifications type 444 stainless steel sheet and strip is covered by the following. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. Stress corrosion cracking of a 304 stainless steel elbow. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. In this study, a layer of adsorbed product film enriched in chromium and nickel was found to form on the metal surface in the solutions. Pdf chloride induced stress corrosion cracking of type 304 and. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of.
It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. However, molybdenum itself does not get incorporated in the passive film. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media. Pitting or crevice corrosion can occur on most stainless steel grades. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies concern the. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Potential and strain rate effects in slow strain rate stress.